Detalle de: ROTATIONAL-ISOMERISM IN 6-BETA-D-GLUCOPYRANOSIDES OF METHYL-1,2,6-THIADIAZIN-3(2H)-ONE 1,1-DIOXIDES
| Title | ROTATIONAL-ISOMERISM IN 6-BETA-D-GLUCOPYRANOSIDES OF METHYL-1,2,6-THIADIAZIN-3(2H)-ONE 1,1-DIOXIDES |
| Abstract |
Glucopyranosides of methyl-1,2,6-thiadiazin-3(2H)-one 1,1-dioxides have been synthesized and their rotational isomerism studied. Two of them exist, in solution, as mixtures of syn : anti rotamers, at room temperature. In the case of the diglucoside, the barriers to rotation about both glycosidic bonds have been calculated by dynamic 13C NMR. |
| Apa Reference | Goya, P., Martinez, A., & Jimeno, M. L. (1990). Rotational isomerism in 6-β-<scp>D</scp>-glucopyranosides of methyl-1,2,6-thiadiazin-3(2H)-one 1,1-dioxides. J. Chem. Soc., Perkin Trans. 2, 5, 783–786. 10.1039/p29900000783 |
| Doi | 10.1039/p29900000783 |
| Publication Date | 1990 |
| Publication Type | Article |
| Researcher | Ana Martínez |
| Ontology | |
| Research Groups | Translational Medicinal and Biological Chemistry |
| Tools |