Detalle de: Boron beats nitrogen: strained boron–boron bonds as (molecular) proton sponges
| Title | Boron beats nitrogen: strained boron–boron bonds as (molecular) proton sponges |
| Abstract |
The basicity and the hydrogen bond (HB) acceptor capability of diborane derivatives of dipyrazole 1 with a B–B bond have been studied theoretically using M06-2x and CCSD(T) methods. The proton affinities of 1b reach 1096 kJ mol −1 . |
| Apa Reference | Alkorta, I., Elguero, J., Montero-Campillo, M. M., Mó, O., & Yáñez, M. (2025). Boron beats nitrogen: strained boron–boron bonds as (molecular) proton sponges. Physical Chemistry Chemical Physics, 27(31), 16447–16453. 10.1039/d5cp02320c |
| Doi | 10.1039/D5CP02320C |
| Publication Date | 2025 |
| Publication Type | Article |
| Researcher | María de la Merced Montero-Campillo |
| Ontology | Invertebrates |
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