Detalle de: Mechanochemical and silica gel-mediated formation of highly electron-poor 1-cyanocarbonylferrocene
| Title | Mechanochemical and silica gel-mediated formation of highly electron-poor 1-cyanocarbonylferrocene |
| Abstract |
Simple manual grinding of solid cyanomethylferrrocene (1) and silica gel provides a facile one-pot access route to prepare unexpected and highly electron-poor metallocene, 1-cyanocarbonylferrocene (2). Electrochemical measurements supported by computational studies reveal that 2 exhibits the highest Fe(II)/Fe(III) oxidation potential reported for mono-substituted ferrocenes. |
| Apa Reference | Nieto, D., Bruña, S., Montero-Campillo, M. M., Perles, J., González-Vadillo, A. M., Méndez, J., Mo, O., & Cuadrado, I. (2013). Mechanochemical and silica gel-mediated formation of highly electron-poor 1-cyanocarbonylferrocene. Chemical Communications, 49(84), 9785. 10.1039/c3cc44619k |
| Doi | 10.1039/c3cc44619k |
| Publication Date | 2013 |
| Publication Type | Article |
| Researcher | María de la Merced Montero-Campillo |
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