Detalle de: An alternative mechanism to explain the ruthenium(II)-catalyzed [2 + 2 + 2] cycloaddition of 1,6-diynes and tricarbonyl compounds
| Title | An alternative mechanism to explain the ruthenium(II)-catalyzed [2 + 2 + 2] cycloaddition of 1,6-diynes and tricarbonyl compounds |
| Abstract |
Density functional theory has been used to study an alternative mechanism for the ruthenium(II)-catalyzed [2 + 2 + 2] cycloaddition between 1,6-diynes and tricarbonyl compounds, proposing a multistep-pathway different from that which we previously reported. The dimerization mechanism to obtain the minority product of the reaction has also been studied in order to analyze the selectivity of this cycloaddition. |
| Apa Reference | Montero-Campillo, M. M., Rodríguez-Otero, J., & Cabaleiro-Lago, E. M. (2009). An Alternative Mechanism to Explain the Ruthenium(II)-Catalyzed [2 + 2 + 2] Cycloaddition of 1,6-Diynes and Tricarbonyl Compounds. The Journal of Physical Chemistry A, 113(32), 9180–9184. 10.1021/jp900962d |
| Doi | 10.1021/jp900962d |
| Publication Date | 17 Jul 2009 |
| Publication Type | Article |
| Researcher | María de la Merced Montero-Campillo |
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