Detalle de: Intramolecular charge transfer and dual fluorescence of 4-(dimethylamino)benzonitrile: ultrafast branching followed by a two-fold decay mechanism
| Title | Intramolecular charge transfer and dual fluorescence of 4-(dimethylamino)benzonitrile: ultrafast branching followed by a two-fold decay mechanism |
| Abstract |
In this contribution we present new experimental and theoretical results for the intramolecular charge transfer (ICT) reaction underlying the dual fluorescence of 4-(dimethylamino)benzonitrile (DMABN), which indicate that the fully twisted ICT (TICT) state is responsible for the time-resolved transient absorption spectrum while a distinct partially twisted ICT (pTICT) structure is suggested for the fluorescent ICT state. |
| Apa Reference | Coto, P.B., Serrano-Andrés, L., Gustavsson, T., Fujiwara, T. & Lim, E.C. (2011). Intramolecular charge transfer and dual fluorescence of 4-(dimethylamino)benzonitrile: ultrafast branching followed by a two-fold decay mechanism. Physical Chemistry Chemical Physics, 13(33), 15182. 10.1039/c1cp21089k |
| Doi | 10.1039/c1cp21089k |
| Publication Date | 2011 |
| Publication Type | Article |
| Researcher | Pedro Braña Coto |
| Ontology | |
| Research Groups | |
| Tools |