Detalle de: The hetero-Diels–Alder addition of sulfur dioxide: structure of the first crystalline sultine. Quantum calculations on the conformations of 6-fluoro-3,6-dihydro-1,2-oxathiine 2-oxides
| Title | The hetero-Diels–Alder addition of sulfur dioxide: structure of the first crystalline sultine. Quantum calculations on the conformations of 6-fluoro-3,6-dihydro-1,2-oxathiine 2-oxides |
| Abstract |
The hetero-Diels–Alder addition of sulfur dioxide to (E)- and (Z)-4-(fluoromethylidene)-3-methylene-2,3-dihydro- naphthalene follows the endo Alder rule. The first example of a crystalline sultine has been obtained. In agreement with high level quantum calculations, (1SR,3SR)-1-fluoro-1,4,5,6-tetrahydronaphtho[2,1-d ][1,2]oxathiine 3-oxide adopts a sofa conformation in its ground state. |
| Apa Reference | Roversi, E., Scopelliti, R., Solari, E., Estoppey, R., Vogel, P., Braña, P., Menéndez, B. & Sordo, J. (2001). The hetero-Diels–Alder addition of sulfur dioxide: structure of the first crystalline sultine. Quantum calculations on the conformations of 6-fluoro-3,6-dihydro-1,2-oxathiine 2-oxides. Chemical Communications(13), 1214-1215. 10.1039/b103096p |
| Doi | 10.1039/b103096p |
| Publication Date | 2001 |
| Publication Type | Article |
| Researcher | Pedro Braña Coto |
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