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Detalle de: Reactivity of hydropersulfides toward the hydroxyl radical unraveled: disulfide bond cleavage, hydrogen atom transfer, and proton-coupled electron transfer

Title Reactivity of hydropersulfides toward the hydroxyl radical unraveled: disulfide bond cleavage, hydrogen atom transfer, and proton-coupled electron transfer
Abstract

Hydropersulfides (RSSH) are highly reactive towards OH radical, and depending on the nature of R substitute, a selective OH substitution with S–S bond cleavage competes with the hydrogen abstraction by the radical.

Apa Reference Anglada, J.M., Crehuet, R., Adhikari, S., Francisco, J.S. & Xia, Y. (2018). Reactivity of hydropersulfides toward the hydroxyl radical unraveled: disulfide bond cleavage, hydrogen atom transfer, and proton-coupled electron transfer. Physical Chemistry Chemical Physics, 20(7), 4793-4804. 10.1039/C7CP07570G
Doi 10.1039/C7CP07570G
Publication Date 2018
Publication Type Article
Researcher Ramon Crehuet Simón
Ontology
Research Groups
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