Detalle de: Interplay of chloride levels and palladium( ii )-catalyzed O -deallenylation bioorthogonal uncaging reactions
| Title | Interplay of chloride levels and palladium( ii )-catalyzed O -deallenylation bioorthogonal uncaging reactions |
| Abstract |
Palladium-mediated C–O bond cleavage in deallenylation shows higher rates at low chloride levels, akin to intracellular conditions, versus reduced efficiency in high chloride concentration, similar to extracellular settings. |
| Apa Reference | Dal Forno, G.M., Latocheski, E., Navo, C.D., Albuquerque, B.L., St John, A.L., Avenier, F., Jiménez-Osés, G. & Domingos, J.B. (2024). Interplay of chloride levels and palladium( ii )-catalyzed O -deallenylation bioorthogonal uncaging reactions. Chemical Science, 15(12), 4458-4465. 10.1039/D3SC06408E |
| Doi | 10.1039/D3SC06408E |
| Publication Date | 2024 |
| Publication Type | Article |
| Researcher | Gonzalo Jiménez-Osés |
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