Detalle de: Mechanistic study of the ring-size modulation in Michael–Dieckmann type reactions of 2-acylaminoacrylates with ketene diethyl acetal
| Title | Mechanistic study of the ring-size modulation in Michael–Dieckmann type reactions of 2-acylaminoacrylates with ketene diethyl acetal |
| Abstract |
An unexpected modulation of the chemoselectivity in the Michael–Dieckmann type reactions of 2-acylaminoacrylates with ketene diethyl acetal is observed, depending on the nature of the acylamino group. Experimental and theoretical studies are presented to offer insights into the origin of this substituent effect in terms of a polar stepwise mechanism. |
| Apa Reference | Avenoza, A., Busto, J.H., Canal, N., García, J.I., Jiménez-Osés, G., Peregrina, J.M. & Pérez-Fernández, M. (2007). Mechanistic study of the ring-size modulation in Michael–Dieckmann type reactions of 2-acylaminoacrylates with ketene diethyl acetal. New J. Chem., 31(2), 224-229. 10.1039/b615220a |
| Doi | 10.1039/b615220a |
| Publication Date | 2007 |
| Publication Type | Article |
| Researcher | Gonzalo Jiménez-Osés |
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